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VB.NET program that uses Val, Asc, AscW
Module Module1
    Sub Main()
        ' Use Val and AscW on char.
        Dim c As Char = "a"c
        Dim i As Integer = Val(c)
        Dim a As Integer = Asc(c)
        Console.WriteLine(c)
        Console.WriteLine(i)
        Console.WriteLine(a)
        ' Another character.
        Dim c2 As Char = "2"c
        Dim i2 As Integer = Val(c2)
        Dim a2 As Integer = AscW(c2) ' AscW is similar to Asc
        Console.WriteLine(c2)
        Console.WriteLine(i2)
        Console.WriteLine(a2)
    End Sub
End Module
Output
a
0
97
2
2
50
Note: The Val, Asc and AscW functions are only available in the VB.NET language, not the C# language.
Tip: If you want to get the number from the Char and turn it into an Integer, the Val function is best.